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The population was 20, at the census. Sulphur is named for the sulfur mines that were operated in the area in the s. In , Professor Eugene W. Hilgard, an experienced geologist who was prospecting for oil and other minerals, conducted exploratory borings in Calcasieu Parish, Louisiana and discovered sulfur in the caprock of a salt dome. However, the sulfur was beneath several hundred feet of muck and quicksand containing deadly hydrogen sulfide gas, which made mining extremely hazardous. Repeated unsuccessful attempts to sink conventional mining shafts in the s and s resulted in the loss of many lives. In , the German immigrant Herman Frasch invented and patented the Frasch Process of mining sulfur, using concentric pipes to pump superheated water into the ground, liquefy the mineral, and force the liquid to the surface with compressed air.

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